Table 1 Solubility of S8 and Sx2− (mM S) in the selected electrolyte solutions and solvents

From: The role of electrocatalytic materials for developing post-lithium metal||sulfur batteries

Solutions/solvents

S8

S82−

S62−

S42−

S32−

S22−

S2−

Refs.

0.98 M LiTFSIa in TEGDMEb

4

6046

34.1

13.9

0.8

100

Li2Sx in THFc

~10,000

~6500

~600

~300

~100

101

Li2Sx in DMSOd

3.9

~14,250

~6000

~1500

~800

~300

<0.2

50

Na2Sx in TEGDME

10,560

7140

2400

39

<6.7

52

K2Sx in DMEe

~10.8

~1.6

53

1.0 M MgTFSI2 and 2.0 M MgCl2 in DME

9.6

<50

13.3

57

AlCl3 with EMICf in a molar ratio of 1.3:1

11.9

18.0

21.1

56

  1. The solubilities of sulfur species are determined at room temperature unless otherwise specified.
  2. aTFSI—bis(trifluoromethanesulfonyl) amide.
  3. bTEGDME—teraglyme.
  4. cTHF—tetrahydrofuran.
  5. dDMSO—dimethyl sulfoxide.
  6. eDME—dimethyl ether.
  7. fEMIC − 1-ethyl-3-methylimidazoliumchloride.