Fig. 1: Interconvertible radical and cationic SUMIs and proposed mechanism. | Nature Communications

Fig. 1: Interconvertible radical and cationic SUMIs and proposed mechanism.

From: Controlled switching thiocarbonylthio end-groups enables interconvertible radical and cationic single-unit monomer insertions and RAFT polymerizations

Fig. 1

Interconvertible radical and cationic SUMIs by switching thiocarbonylthio end-groups between trithiocarbonates to dithiocarbamates, and proposed mechanism for thiocarbonylthio exchange reaction between chain tranfer agents and bis(thiocarbonyl) disulfides.

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