Fig. 1: Schematic summary of the study presented herein.

(left) Schematic representation of the trifunctional macromolecules synthesised in the current study showing L, the distance between terminal and central functional units. (right) Schematic representation of how a varying L is able to impact both the quantum yield of intramolecular cyclisation of the macromolecules and the printability when applied to two-photon microprinting.