Fig. 9: Optimized geometries for the enantiocontrolling TSs (TSHAU(re)‡ and TSHAU(si)‡) and regioicontrolling TSHAS‡ highlighting the important NCIs. | Nature Communications

Fig. 9: Optimized geometries for the enantiocontrolling TSs (TSHAU(re)‡ and TSHAU(si)‡) and regioicontrolling TSHAS‡ highlighting the important NCIs.

From: Chemo-, regio- and enantioselective hydroformylation of trisubstituted cyclopropenes: access to chiral quaternary cyclopropanes

Fig. 9

Key interatomic distances (in Å) and the corresponding electron densities at the bond critical points (ρbcp × 10–2) for various NCIs are given in parentheses. Hydrogen atoms not involved in significant interactions are omitted for improved clarity. a NCIs in enantiocontrolling TSHAU(re)‡; b NCIs in enantiocontrolling TSHAU(si)‡; c NCIs in regioicontrolling TSHAS‡.

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