Fig. 2: Substrate scope for β-fluoroalkyl substituted silanes.
From: Nickel-catalyzed regiodivergent hydrosilylation of α-(fluoroalkyl)styrenes without defluorination
a Reaction conditions A: [a] 1 (0.2 mmol), [Si]-H 2 (0.4 mmol), Ni(cod)2 (5 mol%), PPh3 (5 mol%), 30 °C, in toluene (2.0 mL) under argon, 24 h, L:B value was determined by 19F NMR, isolated yield. [b] 60 °C. [c] L1 (5 mol%) and CsOAc (20 mol%) were used instead of PPh3.
