Table 1 EXAFS fitting parameters of demodulated spectra at \({\phi }_{{{{\rm{PSD}}}}}=324^{\circ }\) using a differential EXAFS model of \({\chi }_{\phi=324^{\circ } }^{{{{\rm{PSD}}}}}={\chi }_{{{{\rm{PdO}}}}}-{\chi }_{{{{\rm{PdPd}}}}\left({{{\rm{PdO}}}}\right)}{-}({\chi }_{{{{\rm{PdAu}}}}}+{\chi }_{{{{\rm{PdPd}}}}})\)

From: Restructuring dynamics of surface species in bimetallic nanoparticles probed by modulation excitation spectroscopy

 

PdO

PdAu

Pd-O

Pd-Pd

Pd-Pd

Pd-Au

\(N\)

\(0.2\)9

\(0.12\)

\(0.3\)3

\(0.5\)8

\({N}_{{{{\rm{rel}}}}}\)

\(7.2\%\)

\(3.0\%\)

\(2.7\%\)

\(4.8\%\)

\(R\left({{{\text{\AA }}}}\right)\)

\(1.96\)

\(2.95\)

\(2.68\)

\(2.73\)