Fig. 2: Cyclic voltammetry experiment and optimization of reaction conditions. | Nature Communications

Fig. 2: Cyclic voltammetry experiment and optimization of reaction conditions.

From: Tailoring photocatalysts to modulate oxidative potential of anilides enhances para-selective electrochemical hydroxylation

Fig. 2

A Oxidation potential of photocatalyst mixed with the substrate under light. red line: used DCFS as photocatalyst. blue line: used Fluorescein as photocatalyst. yellow line: used Eosin Y as photocatalyst. green line: used Acid Red 92 as photocatalyst. grey line: no photocatalyst. B Cyclic voltammetry experiment of N-Boc aniline and DCFS. C Optimization of reaction conditions. D Cyclic voltammetry experiment of 4-N-Boc aminophenol and DCFS. [a] standard conditions: N-Boc aniline 1 (0.6 mmol), 2a (0.3 mmol), DCFS (10 mol%), nBu4NBF4 (1.0 equiv.), TMBA (4.0 equiv.), DMAc (6 mL). CR as an electrode, Blue LEDs, 10 mA, 10 h. [b] Yield of NMR, with 1,3,5-trimethylbenzene as internal standard. [c] Yields of isolated products.

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