Fig. 3: Scope of substrates. | Nature Communications

Fig. 3: Scope of substrates.

From: Tailoring photocatalysts to modulate oxidative potential of anilides enhances para-selective electrochemical hydroxylation

Fig. 3

All values indicate the yield of the isolated product. Reaction conditions: 1 (2.0 equiv.), 2a (0.3 mmol), DCFS (10 mol%), nBu4NBF4 (1.0 equiv.), TMBA (4.0 equiv.), DMAc (6 mL). CR as electrode, 10 mA, Blue LEDs, 10 h. [a] 1a (2.0 equiv.), 2a (6 mmol), DCFS (10 mol%), nBu4NBF4 (1.0 equiv.), TMBA (4.0 equiv.), DMAc (100 mL). CR as the anode, CF as the cathode 10 mA, and Blue LEDs. [b] Derivatization by 6c, refer to the Supplementary Information for details.

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