Fig. 6: Schematic representation of co-assembly process of Ag40, UMP nucleotides, and water.

a DFT (PBE0/def2-SVP)-calculated structure of the Ag40 and UMP co-assembly, dotted lines indicate non-covalent interactions, including N-H···O (black line) and N-H···π (orange line). Color codes: Ag green, S yellow, C gray, N blue, F cyan, O red, H white. b Scheme showing the chiral co-assembly process of Ag40 and UMP mediated by H2O.