Fig. 3: 3D zeolitic-like CSF before and after removal of solvates from channels. | Nature Communications

Fig. 3: 3D zeolitic-like CSF before and after removal of solvates from channels.

From: Buckling cluster-based H-bonded icosahedral capsules and their propagation to a robust zeolite-like supramolecular framework

Fig. 3

a 0D pseudo-icosahedron capsule and edge-sharing pseudo-icosahedron stacking for the formation of a 3D framework. b 3D robust zeolitic-like CSFs in 1 revealing two types of infinite channels (α and β), and 1 transformed by heat into 1-d with open channels (α′ and β′). c Double helix with each helix distinguished by red- or blue copper clusters. Inset: overlay of crystal structures of [Cu5L4((p-F-Ph)3P)4]+ in 1 and 1-d. d Schematic 3D orthogonal double-helical patterns.

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