Fig. 3: Substrate scope of the method for the formation of tri-substituted alkenyl amides. | Nature Communications

Fig. 3: Substrate scope of the method for the formation of tri-substituted alkenyl amides.

From: CO2-promoted photocatalytic aryl migration from nitrogen to carbon for switchable transformation of N-arylpropiolamides

Fig. 3

Reaction conditions: 1 (0.1 mmol), PhSO2Na (0.15 mmol, 1.5 equiv), Ir[(dFCF3ppy)2(bpy)]PF6 (1 mol%), DMF (2 mL), H2O (0.5 mL), 1 atm CO2, 72 W blue LEDs, rt, 24 h. Isolated yields. a48 h. bH2O (1 mL), 48 h.

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