Fig. 3: Reactivity studies of 1.
From: Synthesis and redox catalysis of Carbodiphosphorane ligated stannylene
A Reaction of 1 with Fe2(CO)9 gave complex 2. Oxidative addition reaction of 1 with CH3I and pentafluoropyridine afforded adducts 3 and 4. Compound 5 was formed via ligand metathesis of 4 with LiCl, or via a one-pot reaction by combining 1, pentafluoropyridine and LiCl. B Molecular structures of 2–5 in the solid state (Hydrogen atoms and solvent molecules are omitted for clarity. Thermal ellipsoids are at the 50% probability level).
