Fig. 5: Scope of the catalytic hydrodefluorination of fluoroarenes.
From: Synthesis and redox catalysis of Carbodiphosphorane ligated stannylene
Reactions were performed on a 0.25 mmol scale; Reaction time and yields were reported in parentheses. Yields were calculated by quantitative 19F NMR using 4-fluorotoluene as internal standard, unless stated otherwise. aIn the presence of 0.4 equiv. of PhSiH3. bIsolated yields. cIn the presence of 2.0 equiv. of PhSiH3.
