Fig. 5: Substrate scope: indole-3-carboxamide[a]. | Nature Communications

Fig. 5: Substrate scope: indole-3-carboxamide[a].

From: Catalyst-controlled directing group translocation in the site selective C–H functionalization of 3-carboxamide indoles and metallocarbenes

Fig. 5

[a] Conditions: A solution of 2a (0.2 mmol) in the indicated solvent (0.1 M) was added via syringe pump over 5 h to 1 (0.1 mmol), MLn (2 mol%), AgNTf2 (8 mol%), and AgOAc (4 mol%) in the indicated solvent (0.1 M) at the indicated temperature. See Supplementary Information for detailed reaction conditions.

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