Fig. 6: Mechanistic studies and proposed mechanism.
From: A modular approach to catalytic stereoselective synthesis of chiral 1,2-diols and 1,3-diols
A Stoichiometric reaction with Ar-Ni(II)Br complex. B Catalytic reaction with Ar-Ni(II)Br complex. C Stoichiometric reaction with alkyl-Ni(II)Br complex. D Intramolecular competition experiment of 3ck-D. E Intermolecular competition KIE experiment. F Side-by side KIE experiments. G Determining the reduction potentials of TBADT and L6NiBr2 by cyclic voltammetry. H Proposed mechanism.
