Fig. 3: Scope of the asymmetric domino Heck/Tsuji-Trost reaction of 1 with cyclohexadienes 2.
From: Enantioselective Heck/Tsuji−Trost reaction of flexible vinylic halides with 1,3-dienes
The yields reported represent single runs and have not been reproduced in this work.[a] [a] 1 (0.2 mmol), 2 (0.8 mmol), Pd(CO2tBu)2 (10 mol %), (Sc,Rs)-Xu3 (20 mol%), Ag2SO4 (0.6 equiv), DMAc (1 mL), Ar, 70 °C, 48 h.
