Fig. 2: Structures and melting behaviours of AFI-[Zn(Im)1.68(bIm)0.32] and CAN-[Zn(Im)1.73(bIm)0.27].
From: Highly porous metal-organic framework glass design and application for gas separation membranes
a1H NMR results of AFI-[Zn(Im)1.68(bIm)0.32] and CAN-[Zn(Im)1.73(bIm)0.27]. b XRD patterns of AFI-[Zn(Im)1.68(bIm)0.32], CAN-[Zn(Im)1.73(bIm)0.27], and simulations from the published crystallographic information files (cifs)29. c, d XRD patterns of amorphous MOFs: (c) aTAFI-[Zn(Im)2-x(bIm)x] and agAFI-[Zn(Im)1.68(bIm)0.32], and (d) aTCAN-[Zn(Im)2-x(bIm)x] and agCAN-[Zn(Im)1.55(bIm)0.45]. Enthalpic responses and weight loss of (e) AFI-[Zn(Im)1.68(bIm)0.32] and (f) CAN-[Zn(Im)1.73(bIm)0.27] measured by DSC and TGA separately, with a heating rate of 10 K/min. Thermal amorphization (TA), melting temperature (Tm), and glass transition temperature (Tg) are indicated. The light yellow and blue shaded region highlights the integrated area for the determination of ΔHm.
