Fig. 5: TCP of AQMs in aggregates.
From: High-fidelity topochemical polymerization in single crystals, polycrystals, and solution aggregates
a Illustration of the formation of crystalline polymer fibers via antisolvent-driven self-assembly and subsequent polymerization in aggregates. b CD spectra showing the mirror responses of CM1-s/CM1-r, and CP1-s/CP1-r. c CD spectra showing the mirror responses of CM2-s/CM2-r, and CP2-s/CP2-r. d Low magnification cryo-EM image of CP2-s nanofibers obtained by drop casting the mixture from THF/water. e High-resolution cryo-EM images of CP2-s nanofibers. f Corresponding FFT image, indicating the main-chain periodicity of 1.30 nm and the inter-chain separation of 1.36 nm.
