Fig. 2: The crystalline structure information of TMCM-CdCl3 provided by SC-XRD.
From: Large low-field-driven electrocaloric effect in organic-inorganic hybrid TMCM-CdCl3
At the FE phase, the crystal structure observed from the (a) cL and b aL axis, in which the organic cation TMCM+ is fixed at one specific orientation (fixed). c The schematic of the order-disorder (fixed—freely rotating) change of the organic cation. d The schematic of the structure change of the inorganic CdCl6 octahedron. At the PE phase, the crystal structure observed from the (e) cH and f aH axis, in which the organic cation tumbles randomly between 12 equivalent orientations (freely rotating). C, H, and N atoms are omitted at the PE phase.
