Fig. 4: Photophysical properties of TJU-27-Ru, [Ru(H2dcbpy)3]·Cl2 and TJU-11.
From: A layered lead halide framework intercalated with Ru(bpy)3 for efficient CO2 photoreduction
a PL spectra of TJU-27-Ru and [Ru(H2dcbpy)3]·Cl2. b PL decay curves and fitting plots of TJU-27-Ru and [Ru(H2dcbpy)3]·Cl2. c Two-dimensional pseudo-color TA plot of TJU-27-Ru. d TA kinetic of TJU-27-Ru. e SPV spectra of TJU-27-Ru and TJU-11. f Integrated PL emission intensity of TJU-27-Ru as a function of temperature fitted by the Arrhenius equation. Inset: temperature-dependent PL spectra of TJU-27-Ru. g EIS Nyquist plots of TJU-27-Ru and TJU-11. h Photocurrent responses of TJU-27-Ru and TJU-11. i Schematic presentation showing the LMCT process of TJU-27-Ru based on the Pb2+-carboxylate coordination motif. Source data are provided as a Source Data file.
