Table 4 Comparison of this study with other photocatalytic HDE methods
From: Photocatalyst-free photochemical deuteration via H/D exchange with D2O
Comparison of this study with other photocatalytic HDE methods for the formyl group | |||||
|---|---|---|---|---|---|
Methods | Wang, 202039 | Wang, 202038 | Wang, 202137 | Su, Yu, Ou, 202441 | This work |
Catalyst | TBADT | 4CzIPN | 4CzIPN | TBAFeCl4 | None |
Yield (%) | 73–95 | 50–99 | 49–93 | 55–90 | 41–99 |
D incorporation (%) | 87–96 | 90–98 | 90–99 | 87–99 | 82–97 |
Reaction time | 24 h–4 days | 36 h | 36 h | 12–48 h | 6–48 h |
Light intensity and wavelength | 36 W, 390 nm | 5 W, blue light | 36 W, blue light | 40 W, 390 nm | 14 W, 380 nm |
Comparison of this study with other photocatalytic HDE methods for α-amines | ||||
|---|---|---|---|---|
Methods | MacMillan, 201717 | Wang, 202443 | Wang, 202442 | This study |
Catalyst | Ir(F-Meppy)2(dtbbpy)PF6 or 4CzIPN | 4CzIPN | 4CzIPN | None |
Yield (%) | 59–88 | 80–98 | 80–92 | 57–99 |
D incorporation (%) | 27–90 | 85–100 | 76–100 | 23–96 |
Reaction time | 24 h | 48 h | 48 h | 24–48 h |
Light intensity and wavelength | 34 W, blue light | Two 40 W, blue light | Two 40 W, blue light | 14 W, 380 nm |
Substrates | Tertiary amines | Primary aliphatic amines | Amides | Tertiary and secondary amines |
