Fig. 4: Charge transfer dynamics at the biotic-abiotic interfaces.

a PL spectra of PCN/Ru-SHE biohybrid systems. b PL lifetimes of PCN, PCN-SHE, PCN/Ru, and PCN/Ru-SHE hybrid systems. c Calculated indirect transfer and direct transfer current density of PCN-SHE and PCN/Ru-SHE biohybrids from CV curves. d ELF analysis of PCN/Ru and Heme 10. e Charge density differences at the interface of PCN/Ru and Heme 10. f ELF analysis of PCN/Ru and flavin. g Charge density differences at the interface of PCN/Ru and flavin. The yellow and green regions in (e) and (g) represent the charge accumulation and charge depletion, respectively.