Fig. 2: Substrate scope for cyano group translocation to alkenyl C(sp2)–H site. | Nature Communications

Fig. 2: Substrate scope for cyano group translocation to alkenyl C(sp2)–H site.

From: Cyano group translocation to alkenyl C(sp2)–H site by radical cation catalysis

Fig. 2

aThe reaction conditions were as follows: conducted with substrate (0.30 mmol) using 4CzIPN (1 or 5 mol%), N3 (15 mol%), and (TripS)2 (20 mol%) in CH3CN (1.5 mL) at room temperature for 12–48 h; Isolated yields. b5 mmol scale reaction. cThe diastereomeric ratios (d.r.) of the products are approximately 1:1 determined by 1H NMR. dYields and ratios were determined by 1H NMR.

Back to article page