Abstract
Recent studies have shown that parasitic two-level systems (TLS) in superconducting qubits, which are a leading source of decoherence, can have relaxation times longer than the qubits themselves. However, the standard techniques used to characterize qubit relaxation is only valid for measuring T1 under the Born-Markov approximation and could mask environmental memory effects in practice. Here, we introduce two-timescale relaxometry, a technique to probe the qubit and environment relaxation simultaneously and efficiently. We apply it to high-coherence fluxonium qubits over a frequency range of 0.1-0.4 GHz, and reveal a discrete spectrum of TLS with millisecond lifetimes. Our analysis of the spectrum is consistent with a random distribution of TLS in the aluminum oxide tunnel barrier of the Josephson junction chain of the fluxonium, with a spectral and volumetric density and average electric dipole similar to previous TLS studies at much higher frequencies. Our study suggests that investigating and mitigating TLS in the junction chain is crucial to the development of various types of noise-protected qubits in circuit QED.
Similar content being viewed by others
Data availability
The data used to reproduce the plots within the paper have been deposited in the figshare database under accession code doi.org/10.6084/m9.figshare.30727316.
References
Redfield, A. G. On the theory of relaxation processes. IBM J. Res. Dev. 1, 19–31 (1957).
Shrikant, U. & Mandayam, P. Quantum non-Markovianity: Overview and recent developments. Front. Quant. Sci. Technol. 2 (2023). https://www.frontiersin.org/journals/quantum-science-and-technology/articles/10.3389/frqst.2023.1134583/full.
Aharonov, D., Kitaev, A. & Preskill, J. Fault-tolerant quantum computation with long-range correlated noise. Phys. Rev. Lett. 96, 050504 (2006).
Terhal, B. M. & Burkard, G. Fault-tolerant quantum computation for local non-Markovian noise. Phys. Rev. A 71, 012336 (2005).
Paladino, E., Galperin, Y., Falci, G. & Altshuler, B. 1/f noise: Implications for solid-state quantum information. Rev. Mod. Phys. 86, 361–418 (2014).
Phillips, W. A. Tunneling states in amorphous solids. J. Low. Temp. Phys. 7, 351–360 (1972).
Müller, C., Cole, J. H. & Lisenfeld, J. Towards understanding two-level-systems in amorphous solids: insights from quantum circuits. Rep. Prog. Phys. 82, 124501 (2019).
Glazman, L. & Catelani, G. Bogoliubov quasiparticles in superconducting qubits. SciPost Phys. Lect.Notes 031. https://doi.org/10.21468/SciPostPhysLectNotes.31 (2021).
Odeh, M. et al. Non-Markovian dynamics of a superconducting qubit in a phononic bandgap. Nat. Phys. 21, 406–411 (2025).
Gustavsson, S. et al. Suppressing relaxation in superconducting qubits by quasiparticle pumping. Science 354, 1573–1577 (2016).
Chen, M., Owens, J. C., Putterman, H., Schäfer, M. & Painter, O. Phonon engineering of atomic-scale defects in superconducting quantum circuits. Sci. Adv. 10, eado6240 (2024).
Spiecker, M. et al. Two-level system hyperpolarization using a quantum Szilard engine. Nat. Phys. 19, 1320–1325 (2023).
Liu, B.-J., Wang, Y.-Y., Sheffer, T. & Wang, C. Observation of discrete charge states of a coherent two-level system in a superconducting qubit. Phys. Rev. Lett. 133, 160602 (2024).
Connolly, T. et al. Coexistence of Nonequilibrium Density and Equilibrium Energy Distribution of Quasiparticles in a Superconducting Qubit. Phys. Rev. Lett. 132, 217001 (2024).
Tuokkola, M. et al. Methods to achieve near-millisecond energy relaxation and dephasing times for a superconducting transmon qubit. Nat. Commun. 16, 5421 (2025).
Bland, M. P. et al. Millisecond lifetimes and coherence times in 2D transmon qubits. Nature 647, 343–348 (2025).
Somoroff, A. et al. Millisecond coherence in a superconducting qubit. Phys. Rev. Lett. 130, 267001 (2023).
Manucharyan, V. E., Koch, J., Glazman, L. I. & Devoret, M. H. Fluxonium: single Cooper-pair circuit free of charge offsets. Science 326, 113–116 (2009).
Wang, F. et al. High-coherence fluxonium qubits manufactured with a wafer-scale-uniformity process. Phys. Rev. Appl. 23, 044064 (2025).
Ding, L. et al. High-fidelity, frequency-flexible two-qubit fluxonium gates with a Transmon coupler. Phys. Rev. X. 13, 031035 (2023).
Lin, W.-J. et al. 24 days-stable CNOT Gate on Fluxonium qubits with over 99.9% fidelity. PRX Quantum 6, 010349 (2025).
Zhang, H. et al. Tunable inductive coupler for high-fidelity gates between fluxonium qubits. PRX Quantum 5, 020326 (2024).
Pop, I. M. et al. Coherent suppression of electromagnetic dissipation due to superconducting quasiparticles. Nature 508, 369–372 (2014).
Hazard, T. et al. Nanowire superinductance Fluxonium qubit. Phys. Rev. Lett. 122, 010504 (2019).
Grünhaupt, L. et al. Granular aluminium as a superconducting material for high-impedance quantum circuits. Nat. Mater. 18, 816–819 (2019).
Dumas, M. F. et al. Measurement-induced Transmon ionization. Phys. Rev. X 14, 041023 (2024).
Solomon, I. Relaxation processes in a system of two spins. Phys. Rev. 99, 559–565 (1955).
Spiecker, M., Pavlov, A. I., Shnirman, A. & Pop, I. M. Solomon equations for qubit and two-level systems: Insights into non-Poissonian quantum jumps. Phys. Rev. A 109, 052218 (2024).
Gardiner, C. Handbook of stochastic methods (Springer, 2004), 3rd edn. Chapter 3, “Markov Process”.
Rivas, A., Huelga, S. F. & Plenio, M. B. Entanglement and non-Markovianity of quantum evolutions. Phys. Rev. Lett. 105, 050403 (2010).
Bista, A. et al. Readout-induced leakage of the fluxonium qubit http://arxiv.org/abs/2501.17807 (2025). ArXiv:2501.17807 [quant-ph].
Klimov, P. et al. Fluctuations of energy-relaxation times in superconducting qubits. Phys. Rev. Lett. 121, 090502 (2018).
Burnett, J. J. et al. Decoherence benchmarking of superconducting qubits. npj Quantum Inf. 5, 1–8 (2019).
Lisenfeld, J. et al. Observation of directly interacting coherent two-level systems in an amorphous material. Nat. Commun. 6, 6182 (2015).
Wang, C. et al. Surface participation and dielectric loss in superconducting qubits. Appl. Phys. Lett. 107, 162601 (2015).
Hung, C.-C. et al. Probing hundreds of individual quantum defects in polycrystalline and amorphous alumina. Phys. Rev. Appl. 17, 034025 (2022).
Nguyen, L. B. et al. High-Coherence Fluxonium Qubit. Phys. Rev. X 9, 041041 (2019).
Bao, F. et al. Fluxonium: an alternative qubit platform for high-fidelity operations. Phys. Rev. Lett. 129, 010502 (2022).
Masluk, N. A., Pop, I. M., Kamal, A., Minev, Z. K. & Devoret, M. H. Microwave characterization of Josephson junction arrays: implementing a low loss superinductance. Phys. Rev. Lett. 109, 137002 (2012).
Ranni, A., Havir, H., Haldar, S. & Maisi, V. F. High impedance Josephson junction resonators in the transmission line geometry. Appl. Phys. Lett. 123, 114002 (2023).
Gyenis, A. et al. Experimental realization of a protected superconducting circuit derived from the 0-π Qubit. PRX Quantum 2, 010339 (2021).
Kalashnikov, K. et al. Bifluxon: Fluxon-parity-protected superconducting qubit. PRX Quantum 1, 010307 (2020).
Kou, A. et al. Fluxonium-based artificial molecule with a tunable magnetic moment. Phys. Rev. X. 7, 031037 (2017).
Smith, W. et al. Magnifying quantum phase fluctuations with cooper-pair pairing. Phys. Rev. X. 12, 021002 (2022).
Nathan, F. et al. Self-correcting GKP qubit and gates in a driven-dissipative circuit. http://arxiv.org/abs/2405.05671 (2024).
Gupta, V. et al. Low loss lumped-element inductors made from granular aluminum. http://arxiv.org/abs/2411.12611 (2024).
Gustavsson, S. et al. Improving quantum gate fidelities by using a qubit to measure microwave pulse distortions. Phys. Rev. Lett. 110, 040502 (2013).
Abdurakhimov, L. V. et al. Identification of different types of high-frequency defects in superconducting qubits. PRX Quantum. 3, 040332 (2022).
Zhang, H. et al. Universal fast-flux control of a coherent, low-frequency qubit. Phys. Rev. X. 11, 011010 (2021).
Acknowledgements
We thank E. Dogan for experimental assistance and Y.-Y. Wang for helpful discussions. This research is supported by the US Army Research Office, QC-S5 Program (No. W911-NF-23-10093; Z.-T. Z., D. R., and C. W.) and the US Army Research Office, HiPS Program (No. W911-NF-18-10146; A. S. and V. E. M.). Data analysis is partially supported by the US Department of Energy, Office of Science, National Quantum Information Science Research Centers, Co-design Center for Quantum Advantage under contract DE-SC0012704 (Z.-T. Z., B.-J. L., and C. W.). The planar fluxonium device is designed by T. A. Masum, and it is fabricated and provided by the SQUILL Foundry at MIT Lincoln Laboratory, with funding from the Laboratory for Physical Sciences (LPS) Qubit Collaboratory.
Author information
Authors and Affiliations
Contributions
Z.-T. Z. carried out the measurements, collected the data, and performed the analysis with the assistance of D. R. and B.-J. L. The experimental protocol was initially developed by D. R. C. W., who conceived and supervised the experiment. The 3D device was fabricated by A. S. under the supervision of V. E. M. Z.-T. Z., B.-J. L. and C. W. wrote the manuscript with input from all authors.
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing interests.
Peer review
Peer review information
Nature Communications thanks Haolin Jin, Martin Spiecker, Uri Vool, and the other anonymous reviewer for their contribution to the peer review of this work. A peer review file is available.
Additional information
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary information
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Zhuang, ZT., Rosenstock, D., Liu, BJ. et al. Non-Markovian relaxation rpectroscopy of fluxonium qubits. Nat Commun (2026). https://doi.org/10.1038/s41467-026-69910-2
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41467-026-69910-2


