Fig. 2: Electrosorption valencies for halide ions in the low-coverage regime on the fcc sites of Ag(111) at a fixed potential (ΦE(I) = 4.0 V, ΦE(Br) = 4.1 V and ΦE(Cl) = 4.1 V, see text). | npj Computational Materials

Fig. 2: Electrosorption valencies for halide ions in the low-coverage regime on the fcc sites of Ag(111) at a fixed potential (ΦE(I) = 4.0 V, ΦE(Br) = 4.1 V and ΦE(Cl) = 4.1 V, see text).

From: Electrosorption at metal surfaces from first principles

Fig. 2

The valencies lθ are calculated with the CHE approximation (solid black lines), the full second-order double-layer (DL) correction (dotted blue lines) and the second-order ΔQnet term (dashed red lines) (see Eqs. (25) and (27)). Experimental “integral” electrosorption valencies for the low-coverage regime are from Foresti et al.54 (orange stars).

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