Table 5 A summary of buffers and other chemical systems used to control the pH in glass dissolution tests.

From: Forty years of durability assessment of nuclear waste glass by standard methods

Name

pH range

Interference

Reference

Potassium hydrogen phthalate (C8H5KO4)/HCl

2.2–4.0

Interference from K; may participate in ion exchange

57

HNO3/NH4OH

4.5–5.5

N/A

71

Sodium acetate (C2H3NaO2)/acetic acid (C2H4O2)

3.7–5.6

Interference from sodium

99

H3BO3/LiOH

8–10

Interference from boron and ion exchange with alkali elements (Li)

57,66

TRIS buffer (C4H11NO3)

7–9

May complex with boron

215,216

KOH/KCl

9–11

May participate in ion-exchange reactions with alkali elements

37,61,217

LiOH/LiCl

9–11

May participate in ion-exchange reactions with alkali elements

71,218