Table 1 Evaluation of molecular weight and adhesion upon exposure to aggressive environments

From: Mechanistic elucidation of the molecular weight dependence of corrosion inhibition afforded by polyetherimide coatings

Test/Sample

ASTM D3359 (tape test)

ASTM D2197-13 (scrape test)

Mw (g/mol)

Mn (g/mol)

Number of Entanglements

MW 60,000

 Pellet

  

58,446

26,767

11.1

 As-cast

5B

>10.0 kg

63,447

23,312

12

 Post 150 day

5B

>10.0 kg

58,291

23,399

11

 Post salt-fog

5B

>10.0 kg

58,512

25,477

11.1

MW 50,000

 Pellet

  

47,863

22,938

9.1

 As-cast

5B

>10.0 kg

53,675

14,034

10.2

 Post 150 day

5B

10.0 kg

47,214

20,034

9

 Post salt-fog

4B

10.0 kg

49,676

21,295

9.4

MW 35,000

 Pellet

  

35,415

17,301

6.7

 As-cast

5B

>10 kg

39,576

14,811

7.5

 Post 150 day

5B

7.00 kg

31,786

13,334

6

 Post salt-fog

4B

6.50 kg

34,285

16,220

6.5

  1. ASTM adhesion testing data and GPC results for the three different MW PEI coatings on AA 7075 substrates prior to exposure for control values. ASTM adhesion testing data and GPC results for the three different weighted average molecular weight PEI coatings on AA 7075 substrates after corrosion exposure to 3.5 wt% aqueous solutions of NaCl and ASTM B-117 salt-fog testing. GPC results for commercially available PEI pellets are additionally included for control values.