Table 2 Best fitting value of EIS after passivation for 10 d in SCPS with different pH
pH | Rebar | Rs (Ω·cm2) | Rf (Ω·cm2·104) | CPE1 | Rct (Ω·cm2·105) | CPE2 | Chi-square value (χ2·10−5) | C1 (F·cm−2·10−5) | C2 (F·cm−2·10−6) | ||
|---|---|---|---|---|---|---|---|---|---|---|---|
Y01 (Ω−1·cm2·sn·10−5) | n1 | Y02 (Ω−1·cm2·sn·10−5) | n2 | ||||||||
13.2 | CS | 17.77 ± 1.3 | 4.932 ± 24 | 2.083 ± 0.06 | 0.92 ± 0.3 | 6.704 ± 63 | 2.969 ± 0.04 | 0.81 ± 0.1 | 8.21 ± 0.04 | 2.09 ± 0.02 | 1.07 ± 0.03 |
LNb | 6.56 ± 1.1 | 0.136 ± 23 | 6.519 ± 0.01 | 0.91 ± 0.2 | 0.427 ± 58 | 6.976 ± 0.02 | 0.82 ± 0.3 | 7.45 ± 0.03 | 5.13 ± 0.02 | 5.65 ± 0.05 | |
MNb | 6.83 ± 1.3 | 0.171 ± 21 | 5.811 ± 0.03 | 0.91 ± 0.1 | 6.748 ± 60 | 5.262 ± 0.04 | 0.81 ± 0.2 | 5.32 ± 0.02 | 4.62 ± 0.04 | 3.32 ± 0.03 | |
HNb | 7.16 ± 1.2 | 0.318 ± 24 | 4.212 ± 0.04 | 0.91 ± 0.3 | 7.612 ± 62 | 3.206 ± 0.05 | 0.80 ± 0.2 | 4.53 ± 0.03 | 3.45 ± 0.03 | 1.47 ± 0.03 | |
12.5 | CS | 14.25 ± 1.1 | 2.282 ± 25 | 2.839 ± 0.05 | 0.90 ± 0.2 | 4.502 ± 60 | 5.563 ± 0.02 | 0.81 ± 0.4 | 6.84 ± 0.03 | 2.71 ± 0.02 | 3.61 ± 0.04 |
LNb | 10.91 ± 1.1 | 3.688 ± 24 | 3.514 ± 0.04 | 0.92 ± 0.4 | 5.239 ± 61 | 4.721 ± 0.03 | 0.82 ± 0.2 | 5.54 ± 0.04 | 3.59 ± 0.02 | 3.14 ± 0.04 | |
MNb | 13.67 ± 1.3 | 4.317 ± 23 | 2.459 ± 0.02 | 0.92 ± 0.3 | 7.365 ± 64 | 3.085 ± 0.02 | 0.81 ± 0.2 | 4.31 ± 0.04 | 2.47 ± 0.04 | 1.46 ± 0.02 | |
HNb | 15.81 ± 1.2 | 6.491 ± 22 | 2.069 ± 0.04 | 0.92 ± 0.4 | 8.971 ± 68 | 2.796 ± 0.04 | 0.81 ± 0.4 | 3.64 ± 0.05 | 2.12 ± 0.02 | 1.25 ± 0.03 | |
10.5 | CS | 7.66 ± 1.2 | 1.402 ± 22 | 4.718 ± 0.02 | 0.90 ± 0.2 | 2.728 ± 68 | 6.531 ± 0.04 | 0.82 ± 0.3 | 5.36 ± 0.05 | 4.51 ± 0.03 | 4.23 ± 0.04 |
LNb | 18.77 ± 1.3 | 5.575 ± 24 | 2.273 ± 0.04 | 0.91 ± 0.1 | 8.559 ± 55 | 3.272 ± 0.04 | 0.82 ± 0.5 | 3.82 ± 0.04 | 2.32 ± 0.04 | 1.78 ± 0.03 | |
MNb | 19.87 ± 1.4 | 7.201 ± 23 | 1.906 ± 0.06 | 0.92 ± 0.3 | 10.32 ± 58 | 2.141 ± 0.06 | 0.81 ± 0.3 | 3.01 ± 0.02 | 1.96 ± 0.03 | 1.01 ± 0.05 | |
HNb | 21.91 ± 1.1 | 9.848 ± 22 | 1.665 ± 0.04 | 0.91 ± 0.2 | 13.21 ± 62 | 1.178 ± 0.05 | 0.82 ± 0.3 | 2.43 ± 0.04 | 1.75 ± 0.03 | 0.71 ± 0.02 | |
9.0 | CS | 5.88 ± 1.0 | 0.073 ± 22 | 7.026 ± 0.02 | 0.90 ± 0.5 | 0.257 ± 55 | 8.209 ± 0.03 | 0.80 ± 0.4 | 4.43 ± 0.05 | 5.43 ± 0.03 | 5.96 ± 0.05 |
LNb | 21.99 ± 1.2 | 6.549 ± 22 | 1.769 ± 0.04 | 0.91 ± 0.4 | 9.494 ± 64 | 2.698 ± 0.06 | 0.80 ± 0.2 | 3.24 ± 0.03 | 1.79 ± 0.02 | 0.89 ± 0.04 | |
MNb | 23.19 ± 1.1 | 9.234 ± 21 | 1.545 ± 0.03 | 0.90 ± 0.3 | 13.63 ± 68 | 1.459 ± 0.05 | 0.82 ± 0.1 | 2.24 ± 0.04 | 1.61 ± 0.03 | 0.64 ± 0.03 | |
HNb | 26.26 ± 1.4 | 11.54 ± 24 | 1.189 ± 0.06 | 0.90 ± 0.2 | 21.34 ± 66 | 1.115 ± 0.04 | 0.80 ± 0.3 | 1.56 ± 0.03 | 1.23 ± 0.04 | 0.28 ± 0.02 | |