Fig. 4: Simulated polarizability anisotropy of the aqueous salt solutions. | Nature Chemistry

Fig. 4: Simulated polarizability anisotropy of the aqueous salt solutions.

From: Time-resolved terahertz–Raman spectroscopy reveals that cations and anions distinctly modify intermolecular interactions of water

Fig. 4

a, Total polarizability anisotropy ΔΠ of aqueous solutions of MgCl2 at 1 M (blue), 2 M (green) and 4 M (red) concentrations. The amplitude increases linearly with concentration, as shown in the inset. b, ΔΠ of Na2SO4 solution at 1 M (red) exhibits modestly smaller amplitude relative to that of pure water (black). Red arrows in a and b indicate the increase and decrease of ΔΠ relative to pure water. \(E_{\rm{THz}}^2\), the square of the THz electric field. c,d, Single molecule ΔΠM (blue) and collision-induced ΔΠI (green) components of ΔΠ (red) for MgCl2 solution at 4 M and for Na2SO4 at 1 M, respectively. Notably, while ΔΠI is the dominant contribution in the ΔΠ of the MgCl2 solution, its contribution is minor in the Na2SO4 solution. The shadowed areas indicate standard errors.

Back to article page