Fig. 4: Simulated polarizability anisotropy of the aqueous salt solutions.

a, Total polarizability anisotropy ΔΠ of aqueous solutions of MgCl2 at 1 M (blue), 2 M (green) and 4 M (red) concentrations. The amplitude increases linearly with concentration, as shown in the inset. b, ΔΠ of Na2SO4 solution at 1 M (red) exhibits modestly smaller amplitude relative to that of pure water (black). Red arrows in a and b indicate the increase and decrease of ΔΠ relative to pure water. \(E_{\rm{THz}}^2\), the square of the THz electric field. c,d, Single molecule ΔΠM (blue) and collision-induced ΔΠI (green) components of ΔΠ (red) for MgCl2 solution at 4 M and for Na2SO4 at 1 M, respectively. Notably, while ΔΠI is the dominant contribution in the ΔΠ of the MgCl2 solution, its contribution is minor in the Na2SO4 solution. The shadowed areas indicate standard errors.