Electrochemically induced pH swing can facilitate direct air capture at ambient temperature; however, the energy efficiency is compromised by the oxidation of the redox-active organic molecules. A hybrid flow cell that spatially isolates the oxygen-sensitive materials from air achieves stable CO2 capture from oxygen-containing gas streams with low energy demand.
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References
Haszeldine, R. S. Carbon capture and storage: how green can black be? Science 325, 1647–1652 (2009). A review article that presents the importance of carbon capture to limit climate change.
Massen-Hane, M., Diederichsen, K. M. & Hatton, T. A. Engineering redox-active electrochemically mediated carbon dioxide capture systems. Nat. Chem. Eng. 1, 35–44 (2024). A perspective that presents engineering approaches to increase the performance of redox-active electrochemically mediated CO2 capture systems.
Sharifian, R., Wagterveld, R. M., Digdaya, I. A., Xiang, C. & Vermaas, D. A. Electrochemical carbon dioxide capture to close the carbon cycle. Energy Environ. Sci. 14, 781–814 (2021). A review article that summarizes the main parameters governing electrochemical pH-swing processes for carbon capture.
Jin, S., Wu, M., Gordon, R. G., Aziz, M. J. & Kwabi, D. G. pH swing cycle for CO2 capture electrochemically driven through proton-coupled electron transfer. Energy Environ. Sci. 13, 3706–3722 (2020). This article presents an example of the use of a pH-swing cycle for electrochemical CO2 capture in aqueous electrolytes.
Pang, S. et al. A phenazine-based high-capacity and high-stability electrochemical CO2 capture cell with coupled electricity storage. Nat. Energy 8, 1126–1136 (2023). This article presents a phenazine-based CO2 capture system that uses pH swing coupled with energy storage.
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This is a summary of: Jin, X. et al. Direct air capture of CO2 in an electrochemical hybrid flow cell with a spatially isolated phenazine electrode. Nat. Energy https://doi.org/10.1038/s41560-025-01836-3 (2025).
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A hybrid-flow cell for stable pH-swing-facilitated direct air capture. Nat Energy 10, 1058–1059 (2025). https://doi.org/10.1038/s41560-025-01837-2
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DOI: https://doi.org/10.1038/s41560-025-01837-2