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Stimuli-responsive metal–organic frameworks enabled by intrinsic molecular motion

Nature Materials volume 21, pages 1334–1340 (2022)Cite this article

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Synthetic stimuli-responsive systems have become increasingly sophisticated and elegant at the nanoscale. This Comment discusses how rationally designed molecular systems capable of dynamic motions can be deployed in macroscopically porous metal–organic frameworks and respond to various stimuli.

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Fig. 1: Rationally designed SR-MOFs.
Fig. 2: Stimuli-responsive peptide-MOFs.
Fig. 3: Dynamic characterizations of SR-MOFs.
Fig. 4: Potential applications of SR-MOFs.

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Acknowledgements

This work was supported by the Ministry of Education - Singapore (MOE2018-T2-2-148, MOE2019-T2-1-093), the Energy Market Authority (EMA-EP009-SEGC-020), and the Agency for Science, Technology and Research (U2102d2004, U2102d2012).

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Authors and Affiliations

  1. Department of Chemical & Biomolecular Engineering, National University of Singapore, Singapore, Singapore

    Jinqiao Dong, Vanessa Wee & Dan Zhao

  2. School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai, China

    Jinqiao Dong

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  1. Jinqiao Dong
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  2. Vanessa Wee
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Correspondence to Jinqiao Dong or Dan Zhao.

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Nature Materials thanks Stefan Kaskel and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.

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Dong, J., Wee, V. & Zhao, D. Stimuli-responsive metal–organic frameworks enabled by intrinsic molecular motion. Nat. Mater. 21, 1334–1340 (2022). https://doi.org/10.1038/s41563-022-01317-y

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