Table 6 List of the Certified Materials (CRM) and standards used for the analysis.

From: Biogeochemical parameters collected and analysed during the French cruises of the PIRATA programme in the Guinea Gulf, 1997--2024

Parameters

Certified Reference Materials or standards solutions

Details

Salinity

IAPSO, Normal Standard Seawater

Calibrated in conductivity ratio (K15) and in salinity

Dissolved oxygen

OSIL, Potassium iodate standard solution

Concentration 0.01N

Nutrients

Kanso Technos co, autoclaved natural seawater

Different lots with large ranges of concentrations

pH

A. Dickson lab, tris buffer

pH = 8.094 @ T = 25°C and S = 35

Total alkalinity

A. Dickson lab, sterilized natural seawater

Different batches with a concentration about 2 200 μmole/kg

Phytoplankton pigments

DHI group, pigments in 1 mL solvant vials

Mixed and single pigments vials for control and calibration