Table 1 Result of structural Analysis Obtained from X-ray Rietveld refinement of the materials.
S0 | a(Å) | 2.8632 | c(Å) | 14.1776 | V(Å3) | 100.7 | Error Analysis | |
|---|---|---|---|---|---|---|---|---|
Li | Ni1 | Ni2 | Al | Co | O | Rwp(%) | R(%) | |
Site | 3b | 3b | 3a | 3a | 3a | 6c | 9.52 | 7.02 |
Position | (0, 0, 1/2) | (0, 0, 1/2) | (0, 0, 0) | (0, 0, 0) | (0, 0, 0) | (0, 0, 0.2557) | ||
Occupancy | 0.956 | 0.054 | 0.750 | 0.056 | 0.153 | 0.988 | ||
S2 | a(Å) | 2.8647 | c(Å) | 14.1982 | V(Å 3 ) | 101.1 | Error Analysis | |
Li | Ni1 | Ni2 | Al | Co | O | Rwp(%) | R(%) | |
Site | 3b | 3b | 3a | 3a | 3a | 6c | 9.29 | 7.36 |
Position | (0, 0, 1/2) | (0, 0, 1/2) | (0, 0, 0) | (0, 0, 0) | (0, 0, 0) | (0, 0, 0.2555) | ||
Occupancy | 0.963 | 0.037 | 0.766 | 0.052 | 0.152 | 0.979 | ||
S4 | a(Å) | 2.8651 | c(Å) | 14.1883 | V(Å 3 ) | 100.9 | Error Analysis | |
Li | Ni1 | Ni2 | Al | Co | O | Rwp(%) | R(%) | |
Site | 3b | 3b | 3a | 3a | 3a | 6c | 8.69 | 7.82 |
Position | (0, 0, 1/2) | (0, 0, 1/2) | (0, 0, 0) | (0, 0, 0) | (0, 0, 0) | (0, 0, 0.2554) | ||
Occupancy | 0.987 | 0.013 | 0.792 | 0.057 | 0.152 | 0.999 | ||
S6 | a(Å) | 2.8652 | c(Å) | 14.1918 | V(Å 3 ) | 100.9 | Error Analysis | |
Li | Ni1 | Ni2 | Al | Co | O | Rwp(%) | R(%) | |
Site | 3b | 3b | 3a | 3a | 3a | 6c | 8.48 | 7.64 |
Position | (0, 0, 1/2) | (0, 0, 1/2) | (0, 0, 0) | (0, 0, 0) | (0, 0, 0) | (0, 0, 0.2557) | ||
Occupancy | 0.966 | 0.034 | 0.768 | 0.052 | 0.150 | 0.978 | ||
