Table 1 The elemental composition of the passive film formed on duplex stainless steel before and after hydrogen charging.
Passive film | Composition in wt.% | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Fe | FeO | Fe2O3 | Fe3O4 | FeOOH | Cr | Cr2O3 | Cr(OH)3 | CrO3 | O2− | OH− | H2O | |
Before hydrogen charging | 1.29 | 44.11 | 54.60 | 0 | 0 | 1.87 | 16.80 | 81.32 | 0 | 35.29 | 58.98 | 5.73 |
After hydrogen charging | 1.38 | 0 | 0 | 44.91 | 53.71 | 2.10 | 0 | 58.87 | 39.03 | 11.14 | 75.44 | 4.65 |