Table 1 Summary of formation times obtained for trihydrogen cation production from methanol isotopomers, acetone, and ethylene glycol.
Molecule | Trihydrogen cation | Formation time (fs) | Primary formation pathway (1,2) | Isotope effect? (Yes/No) |
---|---|---|---|---|
CH3OD | H3 + | 97 ± 14 | 1 | No |
CH3OH | H3 + | 98 ± 4 | 1 | No |
Acetone | H3 + | 131 ± 10 | 1 | No |
CD3OD | D3 + | 132 ± 5 | 1 | Yes |
Ethylene glycol | H3 + | 142 ± 5 | 2 | No |
CH3OD | H2D+ | 244 ± 25 | 2 | Yes |