Table 1 Linear Regression Data, Precision, Limits of detection (LODs) and Limits of quantification (LOQs) of the Investigated Compounds
Analyte | Calibration curve | r 2 | Precision (RSD%) | LOD | LOQ | |||
|---|---|---|---|---|---|---|---|---|
Intra-day n = 6 | Inter-day n = 6 | |||||||
Retention time | Peak area | Retention time | Peak area | ng/mL | ng/mL | |||
Sodium danshensu | y = 280.45 x + 58.275 | 0.9991 | 0.06 | 1.11 | 0.22 | 3.78 | 1.94 | 6.39 |
Protocatechuic aldehyde | y = 667.14 x + 128.85 | 0.9992 | 0.07 | 0.80 | 0.15 | 2.43 | 1.19 | 3.91 |
Rosmarinic acid | y = 170.82 x + 30.748 | 0.9996 | 0.07 | 3.59 | 0.23 | 4.57 | 4.25 | 14.03 |
Lithospermic acid | y = 281.12 x + 54.368 | 0.9991 | 0.05 | 1.15 | 0.19 | 2.41 | 3.61 | 11.93 |
Salvianolic acid B | y = 152.62 x + 29.499 | 0.9995 | 0.38 | 2.56 | 0.41 | 2.56 | 4.62 | 15.23 |
Salvianolic acid A | y = 261.54 x + 52.301 | 0.9992 | 0.11 | 1.24 | 0.09 | 4.16 | 3.70 | 12.22 |