Table 2 Summary of crystalographic data for 3–5.

Chemical formula

C₃₄H₃₄I₄Hg₂N₄O₂ · DMSO

C₃₄H₃₄AgF₆N₄O₂P · CH₃CN

C₄₄H₄₀AgF₆N₄O₂P · 0.5DMSO

Formula weight

1517.56

824.54

946.69

Cryst syst

Monoclinic

Orthorhombic

Monoclinic

Space group

P2₁/c

P2₁2₁2₁

C2/c

a, Å

14.689(1)

11.451(7)

29.192(3)

b, Å

15.044(1)

14.521(9)

11.684(1)

c, Å

21.269(2)

21.042(1)

24.881(2)

α, deg

90

90

90

β, deg

97.7(2)

90

93.7 (2)

γ, deg

90

90

90

V, ų

4657.7(9)

3499.3(4)

8468.7(1)

Z

4

4

8

D _calcd, Mg m⁻³

2.164

1.565

1.485

Abs coeff, mm⁻¹

9.315

0.695

0.609

F(000)

2784

1680

3864

Cryst size, mm

0.18 × 0.17 × 0.16

0.18 × 0.17 × 0.15

0.18 × 0.17 × 0.15

θ _min, θ _max, deg

1.66, 25.01

1.70, 25.01

1.64, 25.01

T, K

296(2)

173(2)

296(2)

No. of data collected

23342

18133

24112

No. of unique data

8201

6168

7450

No. of refined params

470

463

570

Goodness-of-fit on F ^{2  a}

1.069

1.043

1.031

R ₁

0.0407

0.0384

0.0523

wR ₂

0.1034

0.0966

0.1480

R ₁

0.0520

0.0427

0.0672

wR ₂

0.1082

0.0999

0.1626