Table 1 Transition temperatures (°C) and associated enthalpies of transition [kJ mol−1] for compounds 1–4, as determined by DSC at a heat/cool rate of 10 °C min−1.
From: Combined Microscopy, Calorimetry and X-ray Scattering Study of Fluorinated Dimesogens
No. | n | Cr | SmY | SmX | SmA | NTB | N | Iso | ||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | 1 | • | 76.1 [44.2] | — | — | (• | 57.1 [0.5] | • | 67.0) [0.3] | — | — | • | 148.3 [1.9] | • |
2 | 2 | • | 79.8 [47.4] | — | — | (• | 58.5 [0.1] | • | 66.7 [0.6] | • | 68.8) [<0.1] | • | 162.9 [2.4] | • |
3 | 3 | • | 74.1 [42.3] | (• | 55.4 [<0.1] | • | 73.6) [0.5] | • | 91.9 [0.4] | — | — | • | 159.6 [1.8] | • |
4 | 4 | • | 74.2 [43.3] | — | — | (• | 61.5) [0.5] | • | 80.4 [0.2] | — | — | • | 158.6 [2.5] | • |
