Figure 5

Calculations of (a) XAS and (b) XMCD of Mn²⁺ A-, Mn²⁺ B-, and Mn³⁺ B-sites. Also shown is a comparison of the XAS measured at 75 K with the sum of the calculated spectra of (i) 62% Mn²⁺ A-, 16% Mn²⁺ B-, and 22% Mn³⁺ B-sites, and (ii) 80% Mn²⁺ A-, 20% Mn²⁺ B-sites. (b) XMCD of Mn²⁺ A-, Mn²⁺ B-, and Mn³⁺ B-sites and a comparison of the XMCD measured at 10 K in ±1 T with the sum of (i) 62% Mn²⁺ A-, 16% Mn²⁺ B-, and 22% Mn³⁺ B-sites, and (ii) 80% Mn²⁺ A-, 20% Mn²⁺ B-sites.