Table 1 Observed species generated from bombardment of H₃C₃H/Ar matrix sample with 200-eV and 2000-eV electrons and their photolytic behaviors.

HC₃H^a

547.6, 3266.2 (3262.9)^b

²⁵

↑^c

—^c

H₃C₃H⁺

583.2 (581.1), 1243.0

²⁴

↑

↓

CH₃

619.9

³³

↑

↓

H₂C₃H^a

686.5, 1061.8, 1935.4, 3028.3, 3310.0

²⁵

↑

↓

HCCH^a

737.2, 3285.7 (3287.9), 3293.3

³⁴

↑

—

C₆H₄

740.7 (743.7), 1008.7, 1040.9,

³⁵

↑

↓

H₂C₃H₂^+a

791.4, 874.4, 1307.3, 2929.0, 3020.8

²⁵

↓

↓

H₂CC(H)CH₂

800.9, 1179.4, 3018.9

³⁶

↓

↑

H₂C₃H₂^a

837.7, 996.2, 1390.6, 1955.3, 1998.4, 3000.1

²⁴

↑

↓

Ar₂H^+a

903.4

²⁴

↓

↓

C₄H₆^a

910.8, 1016.8, 1382.9

³⁷

—

↓

H₂C₃

999.2 (1003.0), 1446.8 (1448.6)

³⁸

↓

—

HC₃^a

1824.8 (1832.6), 3238.3

³⁸

↓

↑

H₂C₃H^−a

1856.4

²⁵

↓

—

C_n

1913.8, 1941.8, 1945.8

↑

—

C₃

2039.2 (2034.8)

²⁵

↓

↑

H₂C₃H⁺

606.8, 1105.2, 1140.6, 1433.2, 2075.2 (multiplet), 3000.6, 3063.4, 3195.3

TW

↓

↓