Table 5 Isotherm parameters on the adsorption of the selected Heavy Metals by P-CNTs.
Isotherm models | Fe | Ni | Cd | Pb | Cu | Zn | Cr | As |
---|---|---|---|---|---|---|---|---|
Langmuir | ||||||||
aL | 312.50 | 10.09 | 66.67 | −625 | 21.65 | 28.90 | 98.04 | −50000 |
bL | 2.31 | −0.02 | −11.06 | −117.25 | −0.004 | 0.1214 | −0.39 | −605 |
Q0 | 135.14 | −625 | −6.03 | 5.33 | −5000 | 238.10 | −250 | 82.65 |
RL | 0.0034 | −1.40 | −0.03 | −0.002 | 1.7313 | 0.0468 | −0.03 | −0.002 |
R2 | 0.0027 | 0.4155 | 0.1501 | 0.0074 | 0.4606 | 0.2226 | 0.2494 | 0.0074 |
Freundlich | ||||||||
Kf | 160.33 | 5.10 | 189103 | 3.66 | 23.12 | 154.10 | 205.35 | 87.68 |
1/nf | −0.045 | 1.388 | 3.257 | −0.277 | 1.008 | 0.068 | 2.223 | −0.200 |
nf | −22.37 | 0.72 | 0.31 | −3.61 | 0.99 | 14.77 | 0.45 | −5.01 |
R2 | 0.0197 | 0.7078 | 0.3710 | 0.2291 | 0.6514 | 0.0350 | 0.5005 | 0.7094 |
Temkin | ||||||||
BT | −2.06 | 345.86 | 31.00 | −2.18 | 241.96 | 12.92 | 480.31 | −32.89 |
bT | −1101 | 6.56 | 73.23 | −1040 | 9.38 | 175.70 | 4.73 | −69.00 |
AT | 3 × 10−32 | 0.1401 | 30.3994 | 0.1759 | 0.3109 | 181441 | 1.6833 | 0.0590 |
R2 | 0.0021 | 0.7904 | 0.5838 | 0.0930 | 0.8191 | 0.0268 | 0.7065 | 0.8767 |
D-R | ||||||||
Kads | −4 × 10−6 | −3 × 10−5 | −1 × 10−7 | 9 × 10−9 | −1 × 10−5 | −3 × 10−5 | −5 × 10−7 | 6 × 10−9 |
qs | 145.27 | 536.20 | 1398.42 | 5.15 | 467.41 | 230.81 | 798.23 | 87.68 |
R2 | 0.0678 | 0.5827 | 0.3581 | 0.181 | 0.6392 | 0.3176 | 0.4434 | 0.7094 |