Figure 3
From: The discovery of Lake Hephaestus, the youngest athalassohaline deep-sea formation on Earth

Ultra-high resolution negative ICR-MS mass spectrometry of the Kryos and Hephaestus brine DOM. (a) Mass-to-charge versus H:C ratio, showing hundreds of low molecular weight organic compounds. (b) van Krevelen diagrams, illustrating remarkable depletion of highly oxygenated (O:C > 0.6) molecular series in the Hephaestus brine DOM. The red line refers to the compositional range of carboxyl-rich alicyclic materials. Bubble colour code for molecular formula series with C, H, O, N and S combinations are defined as follow: CHO (blue), CHOS (green), CHON (orange) and CHONS (red). Bubble areas indicate relative mass peak intensity of each assigned mass ion. (c) Counts of elemental compositions of assigned molecular formulas CHO, CHNO, CHOS and CHNOS. (d) Counts of sulphur atoms in CHOS-containing compounds.