Figure 3
From: The importance of plasmonic heating for the plasmon-driven photodimerization of 4-nitrothiophenol
(a) SERS spectra of 4-NTP after different irradiation times with a laser intensity of 25.5 kW/cm2 (a) at a bath temperature of T = 293 K. (b) Kinetics of the product extracted from the peak area at 1345 cm−1 in a) for different temperatures. The NT temperature is around 75 K higher than the external heating temperature indicated in the legend. (c) Rates extracted from kinetics in (b) (fitting indicated in (b) by dashed lines).
