Table 1 Summary of the mineralogy of primary Au-Ag ores from Limousin (French Massif Central).

From: Geochemistry of Gold Ores Mined During Celtic Times from the North-Western French Massif Central

Ore deposit/

Ore grades (ppm)

Ore Mineralogy (*)

mining site

Sample Id

Au

Ag

Pb

Les Fouilloux (A)

4300

30.6

6

233

stibnite, pyrite, arsenopyrite, Ag-poor tetrahedrite (4.5–4.8 wt % Ag), chalcopyrite, galena, sphalerite, berthierite, jamesonite, gold with Au/Ag ratio: 86/14–80/20

4301

56.4

11.5

156

4302

80.6

9.3

148

4303

39.9

28.3

2890

4306

94.0

9.4

401

4453

82,03

17.4

308

Cros Gallet (A)

4438

306.89

16.3

104

gold, arsenopyrite, lindstromite, native bismuth; two gold populations (Au/Ag ratio): 89/11–87/13 and 81/19

4141

na (**)

na

na

4142

na

na

na

Cros Gallet (M, underground)

4439

1105.85

45

624

gold (Ag = 28 wt%), arsenopyrite, pyrite, galena, chalcopyrite, sphalerite, bournonite and boulangerite

Cros Gallet (M, open pit)

4315

0.31

<0.5

11

pyrite, arsenopyrite

4316-a

0.27

<0.5

9

4320-a

0.15

<0.5

6

4321-a

0.16

<0.5

12

4322

0.33

<0.5

10

4323

0.23

<0.5

12

4324

0.20

<0.5

11

4327

0.34

<0.5

12

4330

0.66

<0.5

18

Lauriéras (A)

4532

0.32

5.2

171.74

pyrite, arsenopyrite, boulangerite/jamesonite, chalcopyrite traces

4534

0.87

2.4

491.87

4536

1.78

2.1

724.68

4538

0.22

0.1

<L.D.

4540

0.03

0.2

5.88

Lauriéras (A/M)

4363

0.03

0.7

48

pyrite, arsenopyrite

4366-a

0.17

7.8

337

4358-a

9.14

80.5

>10000

4541

12.64

5.5

26.88

4537

0.22

0.46

19.39

Lauriéras (M)

4143 A

na

na

na

type 1 gold (Au/Ag = 87/13) with Ag-poor tetrahedrite, (4 wt% Ag), bournonite, boulangerite, jamesonite, galena, sphalerite, chalcopyrite and arsenopyrite

4143 C

na

na

na

4143D

na

na

na

4150

na

na

na

Lauriéras (M)

4144B

na

na

na

type 2 gold (Au/Ag = 51/49) with Ag-rich tetrahedrite (17 wt% Ag), sphalerite, chalcopyrite, galena, pyrite, and arsenopyrite

4144 C

na

na

na

Lauriéras (M)

4149B

na

na

na

type 3 gold (Au/Ag = 75/25) with arsenopyrite

4149 C

na

na

na

Les Renardières (M)

4337

0.28

1.2

15

gold (Au/Ag = 65/35) with Ag-rich tetrahedrite (10–17 wt % Ag), pyrite, sphalerite, chalcopyrite, arsenopyrite, galena, boulangerite, jamesonite, freibergite, acanthite

4342

0.22

1.3

97

La Rochefroide (M)

4349

0.47

1.9

91

pyrite

4350

0.94

5.5

100

4351

0.93

2.9

201

  1. The label (A) means Ancient ores, and the label (M) means Modern ores. (*) Stibnite: Sb2S3; Pyrite: FeS2; Arsenopyrite: FeAsS; Chalcopyrite: CuFeS2; Galena: PbS; Sphalerite: ZnS; Berthierite: FeSb2S4; Jamesonite: Pb4FeSb6S14; Lindstromite: Pb3Cu3Bi7S15; Boulangerite: Pb5Sb4S11; Bournonite: PbCuSbS3; Freibergite: (Ag,Cu,Fe)12(Sb,As)4S13; Acanthite: Ag2S; Tetraedrite: (Cu,Fe)12Sb4S13.
  2. (**) Not analysed.