Table 3 Thermodynamic parameters for the adsorption of Cd(II) onto the four rice straw adsorbents.
Treatments | Temperature (K) | ΔG° (kJ g−1 mol−1) | ΔH° (J g−1 mol−1) | ΔS° (J g−1 mol−1 K−1) | RL |
---|---|---|---|---|---|
Sp | 298 | 13.66 | −27.76 | −0.14 | 0.1988~1 |
308 | 13.74 | 0.1764~1 | |||
318 | 16.44 | 0.3344~1 | |||
Sa | 298 | 6.16 | −15.89 | −0.07 | 0.0119~1 |
308 | 8.21 | 0.0241~1 | |||
318 | 7.64 | 0.0176~1 | |||
Sb | 298 | −0.43 | −206.35 | −0.69 | 0.0008~1 |
308 | 7.73 | 0.0200~1 | |||
318 | 13.39 | 0.1366~1 | |||
Ms | 298 | 10.54 | −45.63 | −0.19 | 0.0658~1 |
308 | 8.78 | 0.0300~1 | |||
318 | 14.31 | 0.1832~1 |