Table 1 Summary of analytical performances of investigated calibration models.
Name | Type | Training set | Testing set | Recovery (%) | RMSEV (nM) | Average precision (%) | LOD (nM) | LOQ (nM) |
|---|---|---|---|---|---|---|---|---|
U1 | Univariate | 10 titration series | 10 titration series | 89 | 397 | 11% | 883 | — |
U2 | Univariate | 8 titration series | 8 titration series | 88 | 237 | 7% | 575 | — |
M50 | Multivariate (PLS) | 10 titration series | 10 titration series | 96 | 138 | 4% | 160 | 470 |
M40 | Multivariate (PLS) | 8 titration series | 10 titration series | 97 | 162 | 5% | 253 | 532 |
M30 | Multivariate (PLS) | 6 titration series | 10 titration series | 98 | 246 | 7% | 346 | 898 |
