Table 3 Dynamic Electrochemical Impedance Parameters for API X120 steel in 3.5 wt% NaCl solution without and with Co2 purging in the absence and presence of various concentrations of PEI corrosion inhibitor.
T, °C | Cinh µmol L−1 | Rs, | Rpo, | Ypo × 10−6 snΩ −1 cm−2 | n1 | Rct, | Yct × 10−6 snΩ −1 cm−2 | n2 | θ | IE, % |
---|---|---|---|---|---|---|---|---|---|---|
20 | Blank | 12.8 | 62.02 | 154.4 | 0.904 | 345.1 | 119.27 | 0.880 | — | — |
25 | 12.2 | 107.4 | 153.1 | 0.906 | 1082 | 68.19 | 0.965 | 0.681 | 68.10 | |
50 | 11.4 | 187.4 | 127.5 | 0.886 | 1398 | 63.19 | 0.968 | 0.753 | 75.31 | |
75 | 13.6 | 274.4 | 126.6 | 0.918 | 1725 | 61.85 | 0.974 | 0.799 | 79.99 | |
100 | 13.29 | 136.7 | 113.9 | 0.884 | 2416 | 49.6 | 0.865 | 0.857 | 85.71 | |
30 | Blank | 14.17 | 66.82 | 286.5 | 0.985 | 308 | 296.4 | 0.857 | — | — |
25 | 14.2 | 19.63 | 231.1 | 0.735 | 822 | 254.1 | 0.849 | 0.625 | 62.53 | |
50 | 13.5 | 31.6 | 223.3 | 0.839 | 1042 | 217.8 | 0.884 | 0.704 | 70.44 | |
75 | 11.18 | 36.09 | 141.7 | 0.891 | 1245 | 166.6 | 0.974 | 0.752 | 75.26 | |
100 | 12.6 | 40.6 | 123.6 | 0.813 | 1715 | 102.7 | 0.836 | 0.820 | 82.04 | |
50 | Blank | 13.05 | 21.05 | 306.5 | 0.722 | 242.7 | 550.1 | 0.734 | — | — |
25 | 9.35 | 14.5 | 250.3 | 0.752 | 428 | 384.6 | 0.838 | 0.432 | 43.29 | |
50 | 11.7 | 44.4 | 225.6 | 0.956 | 532 | 323.9 | 0.965 | 0.543 | 54.37 | |
75 | 11.9 | 20.9 | 165.1 | 0.913 | 662 | 291.6 | 0.946 | 0.633 | 63.33 | |
100 | 11.03 | 29.4 | 137.17 | 0.647 | 858 | 288.1 | 0.829 | 0.717 | 71.71 | |
70 | Blank | 11.14 | 23.5 | 320.6 | 0.608 | 180 | 858.8 | 0.846 | — | — |
25 | 12.4 | 36.4 | 299.3 | 0.678 | 242.7 | 625.1 | 0.966 | 0.258 | 25.83 | |
50 | 12.7 | 47.4 | 249.6 | 0.914 | 313.2 | 570.1 | 0.530 | 0.425 | 42.52 | |
75 | 13.68 | 51.74 | 223.8 | 0.811 | 397.2 | 569.2 | 0.986 | 0.546 | 54.68 | |
100 | 12.39 | 55.4 | 222.7 | 0.592 | 504.2 | 532.5 | 0.986 | 0.642 | 64.29 |