Table 1 Structural paramenters from Rietveld analysis: lattice parameters (a/b, c)T,H, unit cell volume (VT,H), phase weight fraction (fT,H), where T = tin oxide (SnO), H = tin (II) oxyhydroxide (Sn6O4(OH)4).
Samples | a/bT | cT | VT | fT | a/bH | cH | VH | fH |
|---|---|---|---|---|---|---|---|---|
(Å) | (Å) | (Å3) | % | (Å) | (Å) | (Å3) | % | |
H0h45 | — | — | — | — | 7.9359(7) | 9.112(1) | 573.86(5) | 100(1) |
H1h00 | — | — | — | — | 7.9366(7) | 9.112(3) | 573.95(4) | 100(1) |
H2h00 | 3.8024(3) | 4.8353(4) | 69.909(3) | 87.03(3) | 7.950(3) | 9.140(5) | 577.62(8) | 13(1) |
H4h00 | 3.8015(7) | 4.8349(9) | 69.872(2) | 100(2) | — | — | — | — |
H6h00 | 3.8021(6) | 4.8351(8) | 69.895(2) | 100(1) | — | — | — | — |
M0h45 | 3.8012(4) | 4.8331(5) | 69.837(13) | 53(1) | 7.9399(9) | 9.1225(12) | 575.11(12) | 47(1) |
M1h00 | 3.8031(10) | 4.8366(13) | 69.951(3) | 100(1) | — | — | — | — |
M1h30 | 3.8029(18) | 4.8358(21) | 69.936(6) | 100.0(8) | — | — | — | — |
M2h30 | 3.8007(3) | 4.8346(3) | 69.838(8) | 100.0(8) | — | — | — | — |
