Table 1 TOF values of catalysts for dimethylamine borane dehydrogenation.
Catalysts | TOF (h−1) | Conversion (%) | References |
|---|---|---|---|
PdCo@AC | 379.5 | 100 | This study |
Ru(cod)(cot) | 1.6 | 40 | |
Cp2Ti | 12.3 | 100 | |
[Rh(1,5-cod)2]Otf | 12.0 | 95 | |
[RhCl(PHCy2)3] | 2.6 | 100 | |
[Cr(CO)5(thf)] | 13.4 | 97 | |
[Cp*Rh(m-Cl)Cl]2 | 0.9 | 100 | |
PdCo@PVP | 330 | 100 | |
HRh(CO)(PPh3)3 | 0.1 | 5 | |
RuCl3·3H2O | 2.7 | 77 | |
trans-RuMe2(PMe3)4 | 12.4 | 100 | |
[Rh(1,5-cod)m-Cl]2 | 12.5 | 100 | |
[Ru(1,5-cod)Cl2]n | 2.5 | 70 | |
Pt(0)/TBA | 31.24 | 100 | |
RhCl(PPh3)3 | 4.3 | 100 | |
IrCl3 | 0.3 | 25 | |
Pd/C | 2.8 | 95 | |
RhCl3 | 7.9 | 90 | |
[Cr(CO)5(ɳ1-BH3NMe3)] | 19.9 | 97 | |
[RuH(PMe3)(NC2H4PPr2)2] | 1.5 | 100 | |
Ni(skeletal) | 3.2 | 100 | |
[Ir(1,5-cod)m-Cl]2 | 0.7 | 95 | |
Pt(0)/TPA@AC | 34.14 | 100 | |
[Rh(1,5-cod)(dmpe)]PF6 | 1.7 | 95 | |
(Idipp)CuCl | 0.3 | 100 | |
Rh(0)NPs | 60.0 | 100 |
