Table 1 EIS parameters for reinforcement steel in SCPS in the presence of various concentrations of the Q-32 corrosion inhibitor with different pH at 20 °C.
Cinh µmol L−1 | Rs, Ω cm−2 | Rpo, Ω cm−2 | CPEpo | Rct, Ω cm−2 | CPEct | Cdl, μF cm−2 | \(\theta\) | IE, % | ||
---|---|---|---|---|---|---|---|---|---|---|
Ypo × 10–6 sn Ω−1 cm−2 | n1 | Yct × 10–6 sn Ω−1 cm−2 | n2 | |||||||
pH 7 | ||||||||||
Blank | 7.64 | – | – | – | 290 ± 3.15 | 830.7 | 0.593 | 312.73 ± 2.96 | – | – |
5 | 8.56 | – | – | – | 513 ± 2.39 | 617 | 0.576 | 264.56 ± 2.67 | 0.434 | 43.5 |
10 | 9.32 | – | – | – | 712.8 ± 4.87 | 409 | 0.677 | 227.15 ± 4.54 | 0.593 | 59.3 |
15 | 8.46 | – | – | – | 1,040 ± 3.92 | 230.1 | 0.853 | 179.84 ± 3.49 | 0.721 | 72.1 |
20 | 9.29 | – | – | – | 1,210 ± 2.41 | 123.7 | 0.851 | 88.70 ± 2.72 | 0.760 | 76.0 |
pH 9 | ||||||||||
Blank | 8.26 | 23.00 | 822.1 | 0.816 | 340 ± 5.13 | 448.4 | 0.801 | 281.03 ± 4.72 | – | – |
5 | 7.57 | 33.71 | 1,325 | 0.756 | 650.5 ± 4.25 | 359.5 | 0.764 | 229.49 ± 4.24 | 0.477 | 47.7 |
10 | 7.83 | 37.13 | 4,143 | 0.983 | 898.9 ± 7.84 | 281.3 | 0.794 | 196.90 ± 7.39 | 0.621 | 62.2 |
15 | 7.95 | 42.53 | 4,925 | 0.530 | 1,361.8 ± 5.93 | 148.4 | 0.876 | 118.34 ± 5.59 | 0.750 | 75.0 |
20 | 8.58 | 51.25 | 6,036 | 0.872 | 2,163.5 ± 6.71 | 99.5 | 0.647 | 43.042 ± 6.33 | 0.842 | 84.3 |
pH 12 | ||||||||||
Blank | 7.897 | 71.66 | 989.2 | 0.924 | 1,210 ± 4.39 | 109.1 | 0.84 | 74.18 ± 4.14 | –- | –- |
5 | 6.380 | 101.6 | 719.6 | 0.599 | 2,582 ± 8.67 | 77.19 | 0.845 | 57.42 ± 8.13 | 0.531 | 53.1 |
10 | 7.299 | 241.2 | 583.2 | 0.950 | 3,990 ± 7.16 | 47.27 | 0.799 | 31.07 ± 6.73 | 0.696 | 69.7 |
15 | 7.814 | 481.8 | 380.5 | 0.694 | 7,591 ± 7.42 | 37.48 | 0.787 | 26.67 ± 7.01 | 0.840 | 84.1 |
20 | 7.938 | 695.6 | 119.3 | 0.841 | 18,282 ± 6.31 | 31.15 | 0.691 | 24.21 ± 5.95 | 0.933 | 93.4 |